Winning back-to-back titles for the first time since 1984 is likely to prove a rather more arduous challenge for Liverpool.
The 22-year-old German is Liverpool's most-expensive signing ever, ahead of captain Virgil van Dijk who joined for 75 million pounds in 2017.
Ukraine came from behind to beat visitors Belgium 3-1 in the first leg of their Nations League playoff on Thursday
Manchester City and Chelsea both secured their Champions League places with victories on the final day of the English Premier League season and Newcastle United joined them despite stumbling to a last-day defeat.
Manchester City manager Pep Guardiola has said Kevin de Bruyne's hamstring problem is "not a big injury" and believes the midfielder could return to action in around three weeks.
Guardiola optimistic of De Bruyne's quick return
A round-up of Saturday's action in the Premier League.
Kevin de Bruyne came off the bench to inspire Belgium in a 2-1 comeback win over Denmark
Wright blasts Man City's Haaland for throwing ball at Arsenal's Gabriel
VfL Wolfsburg have completed the signing of talented winger Kevin de Bruyne from Chelsea with the Belgian agreeing to a five-year contract, the Bundesliga club said on Saturday.
Kevin De Bruyne had to be replaced by Gabriel Jesus in the 60th minute on Saturday following a collision with Antonio Rudiger.
Belgium coach Marc Wilmots insists Kevin De Bruyne is enjoying his football again and will get even better when his side play Hungary in their Euro 2016 round of 16 clash on Sunday. De Bruyne struggled in Belgium's opening 2-0 defeat by Italy but contributed an assist against Ireland before delivering a midfield masterclass as Wilmots's side secured a place in the second round with a 1-0 win over Sweden.
"I didn't do it before because I was young and I didn't have the profile I have now," De Bruyne, who turns 28 next Thursday on the same day Belgium play England in their final Group G fixture, told RTBF television.
Kevin de Bruyne was hailed as playing football "on another level" by his manager Pep Guardiola after the Belgian maestro orchestrated another Manchester City symphony on Saturday.
Manchester City midfielder Kevin de Bruyne is facing a potentially lengthy spell on the sidelines after he was carried off on a stretcher with a suspected knee ligament injury in Wednesday's League Cup semi-final win over Everton.
Youri Tielemans and Kevin De Bruyne gave Belgium a 2-0 win over Romania in an incredible game full of chances
The 27-year-old Belgium international had joined City squad last week after helping his country progress to the World Cup semi-finals in Russia.
Crystal Palace's Eberechi Eze sparked a massive south London party by scoring the only goal to win the FA Cup 1-0 against Manchester City on Saturday and claim the club's first major trophy in their history.
A dipping long-range strike from Kevin de Bruyne gave Belgium a late 2-1 win away at 10-man Switzerland in a friendly between the two Euro 2016 finalists on Saturday.
ManchesterCity's season began to unravel when Kevin de Bruyne missed 10 matches with a knee injury but as he showed when he scored against Paris St Germain on Tuesday, anything is possible with him back in the team.
A round-up of Saturday's fifth round action in the FA Cup
Sergio Aguero and Kevin De Bruyne put on an attacking masterclass to help City rout Leicester City 5-1.
Manchester City's Matheus Nunes scored deep in injury time to salvage a crucial 2-1 Premier League victory over Aston Villa on Tuesday in their breathless chase for a Champions League berth next season.
Photograph of the World Cup game between Belguim and USA
Chelsea manager Jose Mourinho is adamant Eden Hazard will not be leaving Stamford Bridge any time soon but believes the playmaker's fellow Belgian international Kevin De Bruyne could move in the January transfer window.
"I want to reach the highest level possible as a player and I think the most important thing is that at the end of the season we can be happy and maybe have some titles," playmaker De Bruyne told the City website (www.mcfc.co.uk).
News of all that's transpired on and off the football field
IMAGES from the English Premier League matches played on Saturday.
Images from the Euro 2024 Round of 16 match between France and Belgium, at Dusseldorf Arena, Dusseldorf, Germany, on Monday.
With 12 games remaining Manchester City are in fourth place with 44 points, just five ahead of 10th-placed Fulham.
The former Chelsea player, who now plies his trade with Vfl Wolfsburg in Germany, scored the opener and created the second for Marc Wilmots' side.
Erling Haaland roared back to his best form with a five-goal salvo as Manchester City thumped Luton Town 6-2 at Kenilworth Road to reach the quarter-finals of the FA Cup on Tuesday.
Jude Bellingham topped the men's overall voting, with the Real Madrid and England midfielder receiving 11,176 selections from his peers.
Shubman Gill met some of Manchester City's treble winning stars during their open-top bus parade in Manchester on Monday.
Pep Guardiola drew first blood in his renewed managerial duel with Jose Mourinho as Manchester City deservedly won an absorbing Premier League derby 2-1 against Manchester United at Old Trafford on Saturday.
Kevin De Bruyne, Kelechi Iheanacho, Raheem Sterling and Ilkay Gundogan gave Man City a 4-0 win over Bournemouth before Nolito was sent off.
IMAGES from the Premier League matches played on Sunday
Manchester City clinched a 1-0 victory at Tottenham Hotspur, while Chelsea were held to a 0-0 draw at home by Aston Villa.
In Pep Guardiola's 100th match in charge of the Manchester club, captain De Bruyne led from the front as City outclassed the Gunners, who have now suffered six home games without a win. Images from the EPL matches played on Sunday.
Brazil return to winning ways with dreary win over Ecuador in their World Cup qualifiers.